Difference between revisions of "Template:Isocyanidecomplexes"

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m (Bosslektorkorrektor moved page User:Bosslektorkorrektor/sandbox to Template:Isocyanidecomplexes: publish overview for homoleptic isocyanide complexes)
 
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{{Chembox
+
<div role="navigation" class="mw-collapsible {{#ifeq:{{{state|}}}|collapsed|mw-collapsed|{{{state|uncollapsed}}}}} navbox">
<!-- Images -->
+
<div style="background:{{element color|table title}}; margin: 2px; padding:2px 4px;font-weight:bold;">{{#invoke:navbar|navbar|collapsible=1|[[homoleptic]] alkyl- and aryl- [[transition metal isocyanide complexes]]}}</div><!--
| ImageFile =  
 
| ImageFile2 =  
 
<!-- Names -->
 
| IUPACName = Potassium tetracyanidoborate
 
| OtherNames = Potassium octacyanoborate
 
<!-- Sections -->
 
| Section1 = {{Chembox Identifiers
 
| index_label = anhydrous
 
| CASNo = 17456-18-7
 
| PubChem =
 
| SMILES = O.[K+].[K+].[K+].[K+].N#C[Mo-4](C#N)(C#N)(C#N)(C#N)(C#N)(C#N)C#N
 
| InChI1=1S/8CN.4K.Mo.H2O/c8*1-2;;;;;;/h;;;;;;;;;;;;;1H2/q8*-1;4*+1;+4;
 
| InChIKey1 = JJVZTQPHXSHIOV-UHFFFAOYSA-N
 
| SMILES1 = [C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.[C-]#N.O.[K+].[K+].[K+].[K+].[Mo+4]
 
  }}
 
| Section2 = {{Chembox Properties
 
| Formula = K[B(CN)<sub>4</sub>]
 
| MolarMass = 153.98 g/mol
 
| Appearance = white-yellow powder to crystal
 
| Density =
 
| MeltingPt = 413 °C<ref name="TCIchemicals">{{TCIchemicals|Product-nr.=P2168|Name=Potassium Tetracyanoborate|Datum=11. april 2019}}.</ref>
 
| BoilingPt =
 
| Solubility =
 
  }}
 
| Section3 = {{Chembox Hazards
 
| GHSPictograms = {{GHS07}}
 
| GHSSignalWord = Warning
 
| HPhrases = {{H-phrases|302|315|319|335}}
 
| PPhrases = {{P-phrases|261|305+351+338 }}
 
| MainHazards =  
 
| FlashPt =
 
| AutoignitionPt =
 
  }}
 
}}
 
'''Potassium octacyanomolybdate(IV)''' is the inorganic salt with the formula K<sub>4</sub>[Mo(CN)<sub>8</sub>]. A yellow solid, it is the potassium salt of the homoleptic [[cyanometalate]] with the coordination number eight. The complex [[anion]] consists of a molybdenum cation in the oxidation state IV and eight anionic [[cyanide]] ligands resulting in an overall charge of -4, which is compensated with four potassium cations. K<sub>4</sub>[Mo(CN)<sub>8</sub>] is often found as a dihdydrate.
 
  
== Synthesis ==
+
--><div class="mw-collapsible-content">
A facile one-pot-synthesis for K<sub>4</sub>[Mo(CN)<sub>8</sub>] · 2 H<sub>2</sub>O is the reduction of [[molybdate]] (MoO<sub>4</sub><sup>2-</sup>) with [[potassium borohydride]] (KBH<sub>4</sub> in a solution with [[potassium cyanide]] and [[acetic acid]]. <ref>J. G. Leipoldt, L. D. C. Bok,P. J. Cilliers, "The preparation of Potassium OctacyanomolybdateIV) Dihydrate", Z. anorg. allg. Chem., 1974, volume 409, pp. 343-44.{{DOI|10.1002/zaac.19744090310}}</ref> This synthesis was one of the first syntheses, where the [[molybdate]] is reduced in the same synthetic step, where the [[cyanometalate]] is formed. The yield is typically about 70%. This synthetic route is useful for big batches, because the work-up is more efficent with more substance and of the inexpensive starting materials compared to the second method.
+
{| style="border-spacing:2px;display:block;overflow:auto;width:100%;"
 
+
|- style="line-height:125%; vertical-align:top;"
4 MoO<sub>4</sub><sup>2-</sup> + 32 CN<sup>-</sup> + BH<sub>4</sub><sup>-</sup> + 31 H<sup>+</sup> → 4 [Mo(CN)<sub>8</sub>]<sup>4-</sup> + 16 H<sub>2</sub>O + H<sub>3</sub>BO<sub>3</sub>
+
! style="background:#e8e8e8; width:5%"|[[Alkali metal|1]]
 
+
! style="background:#f0f0f0; width:5%"|[[Alkaline earth metal|2]]
Molybdenum has a high affinity towards [[oxygen]]. To avoid the energy consuming molybdenum-oxygen-bond cleavage, an alternative route to the potassium octacyanotungstate(IV) dihydrate starts from MoCl<sub>4</sub>(Et<sub>2</sub>O)<sub>2</sub> directly from the oxidation state IV, so no reduction is needed in the first step. Also with this route the yield is typically around 70%. <ref>G. Handzlik, M. Magott, B. Sielucka, D. Pinkowicz, "Alternative Synthetic Route to Potassium Octacyanidoniobate(IV ) and I ts Molybdenum Congener", Eur. J. Inorg. Chem., 2016, pp. 4872-77.{{DOI|10.1002/ejic.201600669}}</ref> This synthesis is simpler than the first one and can be made in lower batch sizes than the first synthesis. But the MoCl<sub>4</sub>(Et<sub>2</sub>O)<sub>2</sub> is typically less available than the [[Molybdate]] (MoO<sub>4</sub><sup>2-</sup>).
+
! style="background:#e8e8e8; width:5%"|[[Group 3 element|3]]
 
+
! style="background:#f0f0f0; width:5%"|[[Group 4 element|4]]
MoCl<sub>4</sub>(Et<sub>2</sub>O)<sub>2</sub> + 8 KCN → K<sub>4</sub>[Mo(CN)<sub>8</sub>] + 4 KCl + 2 Et<sub>2</sub>O
+
! style="background:#e8e8e8; width:5%"|[[Group 5 element|5]]
 
+
! style="background:#f0f0f0; width:5%"|[[Group 6 element|6]]
== Redox Chemistry ==
+
! style="background:#e8e8e8; width:5%"|[[Group 7 element|7]]
 
+
! style="background:#f0f0f0; width:5%"|[[Group 8 element|8]]
One electron oxidation of the octacyanomolybadate(IV) leads to the paramagnetic octacyanomolybdate(V), which is a 17 electron complex and often used in [[magnetochemistry]].
+
! style="background:#e8e8e8; width:5%"|[[Group 9 element|9]]
 
+
! style="background:#f0f0f0; width:5%"|[[Group 10 element|10]]
== Protonation ==
+
! style="background:#e8e8e8; width:5%"|[[Group 11 element|11]]
Like many [[cyanometalate]] complexes, octacyanomolybdate(IV) is  sensitive towards strong acids.<ref name="Sigma-Aldrich"/>
+
! style="background:#f0f0f0; width:5%"|[[Group 12 element|12]]
In strong acids the [[cyanide]] ligands are getting protonated, leading to the corresponding [[hydrogen isocyanide]] ligands. These ligands can be substituted by other ligands e. g., H<sub>2</sub>O. Potonation of [Mo(CN)<sub>8</sub>]<sup>4-</sup> leads to the homoleptic [[hydrogen isocyanide]] complex [Mo(CNH)<sub>8</sub>]<sup>4+</sup>.<ref>M. Sellin, V. Marvaud, M. Malischewski, "Isolation and Structural Characterization of Eightfold Protonated Octacyanometalates [M(CNH)<sub>8</sub>]<sup>4+</sup> (M=Mo<sup>IV</sup>, W<sup>IV</sup>) from Superacids", Angew. Chem. Int. Ed., 2020 volume 59, pp. 10519-10522.{{DOI|10.1002/anie.202002366}}</ref>
+
! style="background:#e8e8e8; width:5%"|[[Boron group|13]]
 
+
! style="background:#f0f0f0; width:5%"|[[Carbon group|14]]
{{cyanides}}
+
! style="background:#e8e8e8; width:5%"|[[Pnictogen|15]]
 
+
! style="background:#f0f0f0; width:5%"|[[Chalcogen|16]]
== References ==
+
! style="background:#e8e8e8; width:5%"|[[Halogen|17]]
 
+
! style="background:#f0f0f0; width:5%"|[[Noble gas|18]]
<references />
+
|- style="background-color:#e0e5ea" <!--  PERIOD 1  -->
 
+
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | H
[[Category:Cyano complexes]]
+
| style="background-color:white;border:none" |
[[Category:Coordination compounds]]
+
| style="background-color:white;border:none" colspan=10 rowspan=3 |
[[Category:Molybdenum(IV) compounds]]
+
| style="background-color:white;border:none" colspan=5 |
[[Category:Potassium compounds]]
+
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | He
[[Category:Coordination compounds]]
+
|- style="background-color:#e0e5ea" <!--  PERIOD 2 -->
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Li
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Be
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | B
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | C
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | N
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | O
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | F
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ne
 +
|- style="background-color:#e0e5ea" <!--  PERIOD 3  -->
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Na
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Mg
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Al
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Si
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | P
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | S
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Cl
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ar
 +
|- style="background-color:#e0e5ea" <!--  PERIOD 4 -->
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | K
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ca
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Sc
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ti
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|V(CNXyl)6(-)}},<br>{{chem2|V(CNXyl)6}},<br>{{chem2|V(CNXyl)6(+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Cr(CNMe)6}},<br>{{chem2|Cr(CNMe)7(2+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Mn(CNMe)6(+)}},<br>{{chem2|Mn(CNMe)6(2+)}},<br>{{chem2|Mn(CNMe)6(3+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Fe(CNMe)5}},<br>{{chem2|Fe2(CNMe)9}},<br>{{chem2|Fe(CNMe)6(2+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Co(CNMe)5(+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Ni(CNMe)4(2+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Cu(CNMe)4(+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Zn
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ga
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ge
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | As
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Se
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Br
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Kr
 +
|- style="background-color:#e0e5ea" <!--  PERIOD 5  -->
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Rb
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Sr
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Y
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Zr
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Nb
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Mo(CNMe)7(2+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Tc(CNMe)6(+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ru
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Rh
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Pd(CNMe)4(2+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Ag(CNMe)4(+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Cd
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | In
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Sn
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Sb
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Te
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | I
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Xe
 +
|- style="background-color:#e0e5ea" <!--  PERIOD 6  -->
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Cs
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ba
 +
| style="background: white" | &nbsp;
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Hf
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ta
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|W(CNMe)7(2+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Re(CNMe)6(+)}},<br>{{chem2|Rh(CNMe)6(2+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Os(CNMe)6(2+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Ir(CNMe)4(+)}},<br>{{chem2|Ir(CNMe)5(+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Pt(CNMe)4(2+)}},<br>{{chem2|Pt3(CNEt)6}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | {{chem2|Au(CNMe)2(+)}}
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Hg
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Tl
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Pb
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Bi
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Po
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | At
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Rn
 +
|- style="background-color:#e0e5ea" <!--  PERIOD 7  -->
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Fr
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ra
 +
| style="background: white" | &nbsp;
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Rf
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Db
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Sg
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Bh
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Hs
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Mt
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ds
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Rg
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Cn
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Nh
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Fl
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Mc
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Lv
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ts
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Og
 +
|-
 +
| style="background-color:white;border:none" colspan=2 rowspan=3 |
 +
| style="background-color:white;border:none" |↓
 +
| style="background-color:white;border:none" colspan=14 |
 +
| style="background-color:white;border:none" rowspan=3 |
 +
|- style="background-color:#e0e5ea" <!--  LANTHANIDES  -->
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | La
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ce
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Pr
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Nd
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Pm
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Sm
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Eu
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Gd
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Tb
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Dy
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ho
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Er
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Tm
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Yb
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Lu
 +
|- style="background-color:#e0e5ea" <!--  ACTINIDES  -->
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Ac
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Th
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Pa
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | U
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Np
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Pu
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Am
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Cm
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Bk
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Cf
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Es
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Fm
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Md
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | No
 +
| style="border-top: 1px solid #6e6e8e; border-bottom: 1px solid #6e6e8e;" | Lr
 +
|}
 +
</div></div><noinclude>
 +
{{documentation}}
 +
</noinclude>

Latest revision as of 15:43, 7 August 2020

Template documentation[create]