Difference between revisions of "Template:Infobox phosphorus/sandbox"

From blackwiki
Jump to navigation Jump to search
imported>DePiep
m (deprecated parameter |series, now |category (via JWB))
imported>Andrybak
m (sync with live version)
 
Line 1: Line 1:
 
{{infobox element
 
{{infobox element
|engvar=en-GB
+
|engvar={{{engvar|}}}
 
|name=phosphorus
 
|name=phosphorus
|pronounce={{IPAc-en|ˈ|f|ɒ|s|f|ər|ə|s}}
 
|pronounce 2={{Respell|FOS|fər-əs}}
 
 
|number=15
 
|number=15
 
|symbol=P
 
|symbol=P
 +
|abundance=
 +
|abundance in earth's crust=5.2 (silicon = 100)
 +
|abundance in oceans=
 +
|abundance in solar system=
 
|left=[[silicon]]
 
|left=[[silicon]]
 
|right=[[sulfur]]
 
|right=[[sulfur]]
 
|above=[[nitrogen|N]]
 
|above=[[nitrogen|N]]
 
|below=[[arsenic|As]]
 
|below=[[arsenic|As]]
|category=polyatomic nonmetal
+
|category comment=
|category comment=sometimes considered a [[metalloid]]
 
 
|group=15
 
|group=15
 
|period=3
 
|period=3
 
|block=p
 
|block=p
|category color=
+
|appearance=Colourless, waxy white, yellow, scarlet, red, violet, black
|appearance=colourless, waxy white, yellow, scarlet, red, violet, black
 
 
|image name=PhosphComby.jpg
 
|image name=PhosphComby.jpg
|image name comment=waxy white (yellow cut), red (granules centre left, chunk centre right), and violet phosphorus
 
|image name 2=
 
|image name 2 comment=
 
|atomic mass=30.973761998
 
|atomic mass 2=5
 
|atomic mass comment=
 
|electron configuration=&#91;[[neon|Ne]]&#93; 3s<sup>2</sup> 3p<sup>3</sup>
 
 
|electrons per shell=2, 8, 5
 
|electrons per shell=2, 8, 5
|color=
+
|phase=
|phase=solid
 
 
|phase comment=
 
|phase comment=
 
|density gplstp=
 
|density gplstp=
|density gpcm3nrt=white:&nbsp;1.823 g·cm<sup>−3</sup><br>red:&nbsp;≈&nbsp;2.2–2.34 g·cm<sup>−3</sup><br>violet:&nbsp;2.36 g·cm<sup>−3</sup><br>black:&nbsp;2.69
+
|density gpcm3nrt=white: 1.823 g/cm<sup>3</sup><br>red: ≈2.2–2.34
|density gpcm3nrt 2=
+
|density gpcm3nrt 2=violet: 2.36
|density gpcm3nrt 3=
+
|density gpcm3nrt 3=black: 2.69
 
|density gpcm3mp=
 
|density gpcm3mp=
|melting point K=<!-- (white) 317.4&nbsp;K, (red) ≈ 852&nbsp;K, (black) 883&nbsp;K -->
+
|melting point K=white: 317.3
|melting point C=white:&nbsp;44.2&nbsp;°C<br>black:&nbsp;610
+
|melting point C=44.15
|melting point F=<!-- (white) 112&nbsp;°F, (red) ≈ 1075&nbsp;°F, (black) 1130&nbsp;°F -->
+
|melting point F=111.5
|sublimation point K=<!-- (red) ≈ 689.2–863 &nbsp;K, (violet) 893&nbsp;K -->
+
|melting point comment=<br>red: &sim;860&nbsp;K (&sim;590&nbsp;°C, &sim;1090&nbsp;°F)<ref>{{cite web |url=https://www.britannica.com/science/phosphorus-chemical-element |title=Phosphorus: Chemical Element |work=Encyclopædia Britannica}}</ref><!-- <br>black: 883&nbsp;K (610&nbsp;°C, 1130&nbsp;°F) -->
|sublimation point C=red: ≈&nbsp;416–590&nbsp;°C<br>violet: 620
+
|sublimation point K=red: ≈689.2–863
|sublimation point F=<!-- (red) ≈ 780.8–1094&nbsp;°F, (violet) 1148&nbsp;°F -->
+
|sublimation point C=≈416–590
|boiling point K=<!-- (white) 553.7&nbsp;K -->
+
|sublimation point F=≈780.8–1094
|boiling point C=white:&nbsp;280.5
+
|sublimation point comment=<br>violet: 893&nbsp;K (620&nbsp;°C, 1148&nbsp;°F)
|boiling point F=<!-- (white) 536.9&nbsp;°F -->
+
|boiling point K=white: 553.7
 +
|boiling point C=280.5
 +
|boiling point F=536.9
 
|triple point K=
 
|triple point K=
 
|triple point kPa=
 
|triple point kPa=
Line 66: Line 60:
 
|vapor pressure 100 k 2=704
 
|vapor pressure 100 k 2=704
 
|vapor pressure 2 comment=(red, b.p.&nbsp;431&nbsp;°C)
 
|vapor pressure 2 comment=(red, b.p.&nbsp;431&nbsp;°C)
|crystal structure=simple triclinic
+
|crystal structure=bodycentredcubic
|oxidation states='''5''', 4, 3, 2,<ref>[http://www.webelements.com/webelements/compounds/text/P/H4P2-13445506.html webelements]</ref> 1,<ref>{{cite journal|doi=10.1021/ic060186o|pmid=16903744|title=Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds|year=2006|last1=Ellis|first1=Bobby D.|last2=MacDonald|first2=Charles L. B.|journal=Inorganic Chemistry|volume=45|issue=17|pages=6864–74}}</ref> −1, −2, −3
 
|oxidation states comment=(a mildly [[acid]]ic oxide)
 
 
|electronegativity=2.19
 
|electronegativity=2.19
 
|number of ionization energies=4
 
|number of ionization energies=4
Line 78: Line 70:
 
|covalent radius=107±3
 
|covalent radius=107±3
 
|Van der Waals radius=180
 
|Van der Waals radius=180
|magnetic ordering=white, red, violet, black: [[diamagnetic]]<ref>[http://www-d0.fnal.gov/hardware/cal/lvps_info/engineering/elementmagn.pdf Magnetic susceptibility of the elements and inorganic compounds], in {{RubberBible86th}}</ref>
+
|magnetic ordering=white, red, violet, black: [[diamagnetic]]<ref>{{cite book |url=https://web.archive.org/web/20110303222309/http://www-d0.fnal.gov/hardware/cal/lvps_info/engineering/elementmagn.pdf|chapter=Magnetic susceptibility of the elements and inorganic compounds| editor = Lide, D. R. | title = CRC Handbook of Chemistry and Physics | edition = 86th | location = Boca Raton (FL) | publisher = CRC Press | year = 2005 | isbn = 0-8493-0486-5 }}
 +
</ref>
 
|electrical resistivity=
 
|electrical resistivity=
 
|electrical resistivity at 0=
 
|electrical resistivity at 0=
Line 90: Line 83:
 
|speed of sound rod at 20=
 
|speed of sound rod at 20=
 
|speed of sound rod at r.t.=
 
|speed of sound rod at r.t.=
 +
|magnetic susceptibility= &minus;20.8·10<sup>−6</sup>
 +
|magnetic susceptibility ref= &#x20;(293&nbsp;K)<ref>{{Cite book|title=CRC, Handbook of Chemistry and Physics|last=Weast|first=Robert|publisher=Chemical Rubber Company Publishing|year=1984|isbn=0-8493-0464-4|location=Boca Raton, Florida|pages=E110|quote=|via=}}</ref>
 
|Young's modulus=
 
|Young's modulus=
 
|Shear modulus=
 
|Shear modulus=
Line 97: Line 92:
 
|Vickers hardness=
 
|Vickers hardness=
 
|Brinell hardness=
 
|Brinell hardness=
|CAS number=white:&nbsp;12185-10-3<br>red:&nbsp;7723-14-0
+
|CAS number=7723-14-0
 +
|CAS number comment= (red)<br>12185-10-3 (white)
 
|isotopes=
 
|isotopes=
 
{{Infobox element/isotopes stable | mn=31 | sym=P | na=100% | n=16 |firstlinks=yes}}
 
{{Infobox element/isotopes stable | mn=31 | sym=P | na=100% | n=16 |firstlinks=yes}}
{{infobox element/isotopes decay | mn=32 | sym=P | na=[[synthetic radioisotope|syn]] | hl=14.28 [[day|d]] | dm=[[beta emission|β<sup>−</sup>]] | de=1.709 | link1=sulfur-32 | pn=32|ps=S}}
+
{{infobox element/isotopes decay | mn=32 | sym=P | na=[[trace radioisotope|trace]] | hl=14.28&nbsp;d | dm=[[beta emission|β<sup>−</sup>]] | de=1.709 | link1=sulfur-32 | pn=32|ps=S}}
{{infobox element/isotopes decay | mn=33 | sym=P | na=syn | hl=25.3 d | dm=β<sup>−</sup> | de=0.249 | link1=sulfur-33 | pn=33|ps=S}}
+
{{infobox element/isotopes decay | mn=33 | sym=P | na=trace | hl=25.3&nbsp;d | dm=β<sup>−</sup> | de=0.249 | link1=sulfur-33 | pn=33|ps=S}}
 
|isotopes comment=
 
|isotopes comment=
 
|predicted by=
 
|predicted by=
Line 111: Line 107:
 
|named by=
 
|named by=
 
|named date=
 
|named date=
|history comment label=Recognized as an element by
+
|history comment label=Recognised as an element by
 
|history comment= [[Antoine Lavoisier]]<ref>cf. "[http://web.lemoyne.edu/~giunta/Lavoisier1.html Memoir on Combustion in General]" ''Mémoires de l'Académie Royale des Sciences'' 1777, 592–600. from Henry Marshall Leicester and Herbert S. Klickstein, ''A Source Book in Chemistry 1400–1900'' (New York: McGraw Hill, 1952)</ref> (1777)
 
|history comment= [[Antoine Lavoisier]]<ref>cf. "[http://web.lemoyne.edu/~giunta/Lavoisier1.html Memoir on Combustion in General]" ''Mémoires de l'Académie Royale des Sciences'' 1777, 592–600. from Henry Marshall Leicester and Herbert S. Klickstein, ''A Source Book in Chemistry 1400–1900'' (New York: McGraw Hill, 1952)</ref> (1777)
}}<noinclude>
+
|QID=Q674
 +
}}<!--
 +
 
 +
--><noinclude>
 +
{{Infobox element/element navigation|symbol=P}}
 
{{Template reference list}}
 
{{Template reference list}}
{documentation|1=Template:Infobox element/doc}}
+
One of these is a [[WP:REFNAME|named reference]]. It may be cited in the containing article as
 +
*<nowiki><ref name="CIAAW2013" /></nowiki> for the source ''Atomic weights of the elements 2013'' (from subtemplates used by {{tl|Infobox element}})
 +
{{documentation|1=Template:Infobox element/doc}}
 +
[[Category:Templates that generate named references]]
 
</noinclude>
 
</noinclude>

Latest revision as of 10:27, 4 August 2020

[[Category:Template:Pagetype with short description]]

Phosphorus, 15P
PhosphComby.jpg
waxy white (yellow cut), red (granules centre left, chunk centre right), and violet phosphorus
Phosphorus
Pronunciation/ˈfɒsfərəs/ (Template:Respell)
AppearanceColourless, waxy white, yellow, scarlet, red, violet, black
Standard atomic weight Ar, std(P)Template:Val[1]
Abundance
in the Earth's crust5.2 (silicon = 100)
Phosphorus in the periodic table
Template:Periodic table (32 columns, micro) N

P

As
siliconphosphorussulfur
Atomic number (Z)15
Groupgroup 15 (pnictogens)
Periodperiod 3
Block  p-block
Electron configuration[Ne] 3s2 3p3
Electrons per shell2, 8, 5
Physical properties
Phase at STPsolid
Melting pointwhite: 317.3 K ​(44.15 °C, ​111.5 °F)
red: ∼860 K (∼590 °C, ∼1090 °F)[2]
Boiling pointwhite: 553.7 K ​(280.5 °C, ​536.9 °F)
Sublimation pointred: ≈689.2–863 K ​(≈416–590 °C, ​≈780.8–1094 °F)
violet: 893 K (620 °C, 1148 °F)
Density (near r.t.)white: 1.823 g/cm3
red: ≈2.2–2.34 g/cm3
violet: 2.36 g/cm3
black: 2.69 g/cm3
Heat of fusionwhite: 0.66 kJ/mol
Heat of vaporizationwhite: 51.9 kJ/mol
Molar heat capacitywhite: 23.824 J/(mol·K)
Vapor pressure (white)
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 279 307 342 388 453 549
vapor pressure (red, b.p. 431 °C)
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 455 489 529 576 635 704
Atomic properties
Oxidation states−3, −2, −1, 0,[3] +1,[4] +2, +3, +4, +5 (a mildly acidic oxide)
ElectronegativityPauling scale: 2.19
Ionization energies
  • 1st: 1011.8 kJ/mol
  • 2nd: 1907 kJ/mol
  • 3rd: 2914.1 kJ/mol
  • (more)
Covalent radius107±3 pm
Van der Waals radius180 pm
Color lines in a spectral range
Spectral lines of phosphorus
Other properties
Natural occurrenceprimordial
Crystal structurebody-centered cubic (bcc)
Bodycentredcubic crystal structure for phosphorus
Thermal conductivitywhite: 0.236 W/(m·K)
black: 12.1 W/(m·K)
Magnetic orderingwhite, red, violet, black: diamagnetic[5]
Magnetic susceptibility−20.8·10−6 cm3/mol (293 K)[6]
Bulk moduluswhite: 5 GPa
red: 11 GPa
CAS Number7723-14-0 (red)
12185-10-3 (white)
History
DiscoveryHennig Brand (1669)
Recognised as an element byAntoine Lavoisier[7] (1777)
Main isotopes of phosphorus
[[Isotope|IsoTemplate:Shytope]] [[Natural abundance|AbunTemplate:Shydance]] Half-life (t1/2) Decay mode [[Decay product|ProTemplate:Shyduct]]
31P 100% stable
32P trace 14.28 d β 32S
33P trace 25.3 d β 33S
Category Category: Phosphorus
| references
Si ←

i'box Si

iso
15
P (E)
→ S

i'box S

  Data sets read by {{Infobox element}}
Name and identifiers
Top image (caption, alt)
Pronunciation
Category (enwiki)
Standard atomic weight
  most stable isotope
Natural occurrence
Phase at STP
Oxidation states
Spectral lines image
Electron configuration (cmt, ref)
Term symbol * (cmt, ref)
Wikidata *
* Not used in {{Infobox element}} (2019-02-03)
See also {{Infobox element/symbol-to--navbox}}

References

  1. Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
  2. "Phosphorus: Chemical Element". Encyclopædia Britannica.
  3. Wang, Yuzhong; Xie, Yaoming; Wei, Pingrong; King, R. Bruce; Schaefer, Iii; Schleyer, Paul v. R.; Robinson, Gregory H. (2008). "Carbene-Stabilized Diphosphorus". Journal of the American Chemical Society. 130 (45): 14970–1. doi:10.1021/ja807828t. PMID 18937460.
  4. Ellis, Bobby D.; MacDonald, Charles L. B. (2006). "Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds". Inorganic Chemistry. 45 (17): 6864–74. doi:10.1021/ic060186o. PMID 16903744.
  5. Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
  6. Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
  7. cf. "Memoir on Combustion in General" Mémoires de l'Académie Royale des Sciences 1777, 592–600. from Henry Marshall Leicester and Herbert S. Klickstein, A Source Book in Chemistry 1400–1900 (New York: McGraw Hill, 1952)

One of these is a named reference. It may be cited in the containing article as

  • <ref name="CIAAW2013" /> for the source Atomic weights of the elements 2013 (from subtemplates used by {{Infobox element}})

Lua error: Internal error: The interpreter has terminated with signal "24".