Difference between revisions of "Template:Infobox phosphorus"
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|electrons per shell=2, 8, 5 | |electrons per shell=2, 8, 5 | ||
|color= | |color= | ||
| − | |phase= | + | |phase=solid |
|phase comment= | |phase comment= | ||
|density gplstp= | |density gplstp= | ||
| Line 70: | Line 70: | ||
|vapor pressure comment 2=(red, bp. 431 °C) | |vapor pressure comment 2=(red, bp. 431 °C) | ||
|crystal structure= | |crystal structure= | ||
| − | |oxidation states='''5''', 4, 3, 2<ref>[http://www.webelements.com/webelements/compounds/text/P/H4P2-13445506.html webelements]</ref>, 1 <ref>{{cite journal|doi=10.1021/ic060186o|pmid=16903744|title=Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds|year=2006|last1=Ellis|first1=Bobby D.|last2=MacDonald|first2=Charles L. B.|journal=Inorganic Chemistry|volume=45|issue=17|pages=6864–74}}</ref>, | + | |oxidation states='''5''', 4, 3, 2<ref>[http://www.webelements.com/webelements/compounds/text/P/H4P2-13445506.html webelements]</ref>, 1 <ref>{{cite journal|doi=10.1021/ic060186o|pmid=16903744|title=Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds|year=2006|last1=Ellis|first1=Bobby D.|last2=MacDonald|first2=Charles L. B.|journal=Inorganic Chemistry|volume=45|issue=17|pages=6864–74}}</ref>, −1, −2, −3 |
|oxidation states comment=mildly [[acid]]ic oxide | |oxidation states comment=mildly [[acid]]ic oxide | ||
|electronegativity=2.19 | |electronegativity=2.19 | ||
| Line 81: | Line 81: | ||
|covalent radius=[[1 E-10 m|107±3]] | |covalent radius=[[1 E-10 m|107±3]] | ||
|Van der Waals radius=[[1 E-10 m|180]] | |Van der Waals radius=[[1 E-10 m|180]] | ||
| − | |magnetic ordering= (white,red,violet,black) [[diamagnetic]]<ref>[http://www-d0.fnal.gov/hardware/cal/lvps_info/engineering/elementmagn.pdf Magnetic susceptibility of the elements and inorganic compounds], in | + | |magnetic ordering= (white,red,violet,black) [[diamagnetic]]<ref>[http://www-d0.fnal.gov/hardware/cal/lvps_info/engineering/elementmagn.pdf Magnetic susceptibility of the elements and inorganic compounds], in {{RubberBible86th}}</ref> |
|electrical resistivity= | |electrical resistivity= | ||
|electrical resistivity at 0= | |electrical resistivity at 0= | ||
Revision as of 23:32, 13 January 2012
[[Category:Template:Pagetype with short description]]
![]() waxy white (yellow cut), red (granules centre left, chunk centre right), and violet phosphorus | |||||||||||||||||||||
| Phosphorus | |||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Pronunciation | /ˈfɒsfərəs/ | ||||||||||||||||||||
| Appearance | colorless, waxy white, yellow, scarlet, red, violet, black | ||||||||||||||||||||
| Standard atomic weight Ar, std(P) | Template:Val[1] | ||||||||||||||||||||
| Phosphorus in the periodic table | |||||||||||||||||||||
| |||||||||||||||||||||
| Atomic number (Z) | 15 | ||||||||||||||||||||
| Group | group 15 (pnictogens) | ||||||||||||||||||||
| Period | period 3 | ||||||||||||||||||||
| Block | p-block | ||||||||||||||||||||
| Electron configuration | [Ne] 3s2 3p3 | ||||||||||||||||||||
| Electrons per shell | 2, 8, 5 | ||||||||||||||||||||
| Physical properties | |||||||||||||||||||||
| Phase at STP | solid | ||||||||||||||||||||
| Density (near r.t.) | (white) 1.823, (red) ≈ 2.2 – 2.34, (violet) 2.36, (black) 2.69 g/cm3 | ||||||||||||||||||||
| Triple point | (red) 862.7 K, 4367 kPa | ||||||||||||||||||||
| Heat of fusion | (white) 0.66 kJ/mol | ||||||||||||||||||||
| Heat of vaporization | (white) 12.4 kJ/mol | ||||||||||||||||||||
| Molar heat capacity | (white) 23.824 J/(mol·K) | ||||||||||||||||||||
Vapor pressure (white)
| |||||||||||||||||||||
vapor pressure
| |||||||||||||||||||||
| Atomic properties | |||||||||||||||||||||
| Oxidation states | −3, −2, −1, 0,[2] +1,[3] +2, +3, +4, +5 (a mildly acidic oxide) | ||||||||||||||||||||
| Electronegativity | Pauling scale: 2.19 | ||||||||||||||||||||
| Ionization energies |
| ||||||||||||||||||||
| Covalent radius | 107±3 pm | ||||||||||||||||||||
| Van der Waals radius | 180 pm | ||||||||||||||||||||
| Spectral lines of phosphorus | |||||||||||||||||||||
| Other properties | |||||||||||||||||||||
| Natural occurrence | primordial | ||||||||||||||||||||
| Thermal conductivity | (white) 0.236, (black) 12.1 W/(m·K) | ||||||||||||||||||||
| Magnetic ordering | (white,red,violet,black) diamagnetic[4] | ||||||||||||||||||||
| Bulk modulus | (white) 5, (red) 11 GPa | ||||||||||||||||||||
| CAS Number | 7723-14-0 | ||||||||||||||||||||
| Main isotopes of phosphorus | |||||||||||||||||||||
| |||||||||||||||||||||
[[Category:Infobox templates|Template:Remove first word]]
| data m.p. cat | |||||
|---|---|---|---|---|---|
| in | calc from C | diff | report | ref | |
| C | 44.2 | — | — | ||
| K | String Module Error: Target string is empty | 317.3 | Expression error: Unrecognized punctuation character "[". | Expression error: Unexpected < operator. | |
| F | String Module Error: Target string is empty | 111.6 | Expression error: Unrecognized punctuation character "[". | Expression error: Unexpected < operator. | Template:Subpage other |
| max precision | 1 | ||||
| WD | Template:Wikidata Script error: No such module "EditAtWikidata". | Template:Wikidata | |||
| input | C: (white) 44.2 °C, (black) 610, K: , F: | ||||
| comment | |||||
| data b.p. cat | |||||
|---|---|---|---|---|---|
| in | calc from C | diff | report | ref | |
| C | 280.5 | — | — | ||
| K | String Module Error: Target string is empty | 553.6 | Expression error: Unrecognized punctuation character "[". | Expression error: Unexpected < operator. | |
| F | String Module Error: Target string is empty | 536.9 | Expression error: Unrecognized punctuation character "[". | Expression error: Unexpected < operator. | Template:Subpage other |
| max precision | 1 | ||||
| WD | Template:Wikidata Script error: No such module "EditAtWikidata". | Template:Wikidata | |||
| input | C: (white) 280.5, K: , F: | ||||
| comment | |||||
References
- ↑ Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
- ↑ Wang, Yuzhong; Xie, Yaoming; Wei, Pingrong; King, R. Bruce; Schaefer, Iii; Schleyer, Paul v. R.; Robinson, Gregory H. (2008). "Carbene-Stabilized Diphosphorus". Journal of the American Chemical Society. 130 (45): 14970–1. doi:10.1021/ja807828t. PMID 18937460.
- ↑ Ellis, Bobby D.; MacDonald, Charles L. B. (2006). "Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds". Inorganic Chemistry. 45 (17): 6864–74. doi:10.1021/ic060186o. PMID 16903744.
- ↑ Magnetic susceptibility of the elements and inorganic compounds, in Template:RubberBible86th
- ↑ webelements
- ↑ Ellis, Bobby D.; MacDonald, Charles L. B. (2006). "Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds". Inorganic Chemistry. 45 (17): 6864–74. doi:10.1021/ic060186o. PMID 16903744. no-break space character in
|title=at position 22 (help)

