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Neptunium, 93 Np File:Np sphere.jpg Neptunium Pronunciation (Template:Respell ) Appearance silvery metallic Mass number [237] Neptunium in the periodic table
Atomic number (Z ) 93 Group group n/a Period period 7 Block f-block Electron configuration [Rn ] 5f4 6d1 7s2 Electrons per shell 2, 8, 18, 32, 22, 9, 2 Physical properties Phase at STP solid Melting point 912±3 K (639±3 °C, 1182±5 °F) Boiling point 4447 K (4174 °C, 7545 °F) (extrapolated) Density (near r.t. ) alpha: 20.45 g/cm3 [1] accepted standard value: 19.38 g/cm3 Heat of fusion 5.19 kJ/mol Heat of vaporization 336 kJ/mol Molar heat capacity 29.46 J/(mol·K) Vapor pressure
P (Pa)
1
10
100
1 k
10 k
100 k
at T (K)
2194
2437
Atomic properties Oxidation states +2, +3, +4,[2] +5 , +6, +7 (an amphoteric oxide) Electronegativity Pauling scale: 1.36 Ionization energies Atomic radius empirical: 155 pm Covalent radius 190±1 pm Spectral lines of neptuniumOther properties Natural occurrence from decay Crystal structure orthorhombic Thermal conductivity 6.3 W/(m·K) Electrical resistivity 1.220 µΩ·m (at 22 °C) Magnetic ordering paramagnetic [3] CAS Number 7439-99-8 History Naming after planet Neptune , itself named after Roman god of the sea Neptune Discovery Edwin McMillan and Philip H. Abelson (1940) Main isotopes of neptunium
16x16px Category: Neptunium | references
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References
These references will appear in the article, but this list appears only on this page.
↑ Sanchez, Rene G.; Loaiza, David J.; Kimpland, Robert H.; Hayes, David K.; Cappiello, Charlene C.; Myers, William L.; Jaegers, Peter J.; Clement, Steven D.; Butterfield, Kenneth B. "Criticality of a 237 Np Sphere" (PDF) . Japanese Atomic Energy Agency. Retrieved 2014-08-06 .
↑ Np(II), (III) and (IV) have been observed, see Dutkiewicz, Michał S.; Apostolidis, Christos; Walter, Olaf; Arnold, Polly L (2017). "Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding" . Chem. Sci . 8 (4): 2553–2561. doi :10.1039/C7SC00034K . PMC 5431675 . PMID 28553487 .
↑ Magnetic susceptibility of the elements and inorganic compounds , in Handbook of Chemistry and Physics 81st edition, CRC press.
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