Template:Infobox phosphorus
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[[Category:Template:Pagetype with short description]]
waxy white (yellow cut), red (granules centre left, chunk centre right), and violet phosphorus | |||||||||||||||||||||
| Phosphorus | |||||||||||||||||||||
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| Pronunciation | /ˈfɒsfərəs/ | ||||||||||||||||||||
| Appearance | waxy white, yellow, red, violet, black metallic-looking | ||||||||||||||||||||
| Standard atomic weight Ar, std(P) | Template:Val[1] | ||||||||||||||||||||
| Abundance | |||||||||||||||||||||
| in the Earth's crust | 5.2 (silicon = 100) | ||||||||||||||||||||
| [[Category:Infobox templates|Template:Remove first word]] | |||||||||||||||||||||
| Phosphorus in the periodic table | |||||||||||||||||||||
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| Atomic number (Z) | 15 | ||||||||||||||||||||
| Group | group 15 (pnictogens) | ||||||||||||||||||||
| Period | period 3 | ||||||||||||||||||||
| Block | p-block | ||||||||||||||||||||
| Electron configuration | [Ne] 3s2 3p3 | ||||||||||||||||||||
| Electrons per shell | 2, 8, 5 | ||||||||||||||||||||
| Physical properties | |||||||||||||||||||||
| Phase at STP | solid | ||||||||||||||||||||
| Melting point | white: 317.3 K (44.15 °C, 111.5 °F) red: ∼860 K (∼590 °C, ∼1090 °F)[2] | ||||||||||||||||||||
| Boiling point | white: 553.7 K (280.5 °C, 536.9 °F) | ||||||||||||||||||||
| Sublimation point | red: ≈689.2–863 K (≈416–590 °C, ≈780.8–1094 °F) violet: 893 K (620 °C, 1148 °F) | ||||||||||||||||||||
| Density (near r.t.) | white: 1.823 g/cm3 red: ≈2.2–2.34 g/cm3 violet: 2.36 g/cm3 black: 2.69 g/cm3 | ||||||||||||||||||||
| Heat of fusion | white: 0.66 kJ/mol | ||||||||||||||||||||
| Heat of vaporization | white: 51.9 kJ/mol | ||||||||||||||||||||
| Molar heat capacity | white: 23.824 J/(mol·K) | ||||||||||||||||||||
Vapor pressure (white)
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vapor pressure (red, b.p. 431 °C)
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| Atomic properties | |||||||||||||||||||||
| Oxidation states | −3, −2, −1, 0,[3] +1,[4] +2, +3, +4, +5 (a mildly acidic oxide) | ||||||||||||||||||||
| Electronegativity | Pauling scale: 2.19 | ||||||||||||||||||||
| Ionization energies |
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| Covalent radius | 107±3 pm | ||||||||||||||||||||
| Van der Waals radius | 180 pm | ||||||||||||||||||||
| Spectral lines of phosphorus | |||||||||||||||||||||
| Other properties | |||||||||||||||||||||
| Natural occurrence | primordial | ||||||||||||||||||||
| Crystal structure | body-centered cubic (bcc) | ||||||||||||||||||||
| Thermal conductivity | white: 0.236 W/(m·K) black: 12.1 W/(m·K) | ||||||||||||||||||||
| Magnetic ordering | white, red, violet, black: diamagnetic[5] | ||||||||||||||||||||
| Magnetic susceptibility | −20.8·10−6 cm3/mol (293 K)[6] | ||||||||||||||||||||
| Bulk modulus | white: 5 GPa red: 11 GPa | ||||||||||||||||||||
| CAS Number | 7723-14-0 (red) 12185-10-3 (white) | ||||||||||||||||||||
| History | |||||||||||||||||||||
| Discovery | Hennig Brand (1669) | ||||||||||||||||||||
| Recognised as an element by | Antoine Lavoisier[7] (1777) | ||||||||||||||||||||
| Main isotopes of phosphorus | |||||||||||||||||||||
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[[Category:Infobox templates|Template:Remove first word]]
| data m.p. cat | |||||
|---|---|---|---|---|---|
| in | calc from C | diff | report | ref | |
| C | 44.15 | — | — | ||
| K | 317.3 | 317.30 | 0 | ||
| F | 111.5 | 111.47 | 0.03 | delta | Template:Subpage other |
| max precision | 2 | ||||
| WD | Template:Wikidata Script error: No such module "EditAtWikidata". | Template:Wikidata | |||
| input | C: 44.15, K: white: 317.3, F: 111.5 | ||||
| comment | red: ∼860 K (∼590 °C, ∼1090 °F)[2] | ||||
| data b.p. cat | |||||
|---|---|---|---|---|---|
| in | calc from C | diff | report | ref | |
| C | 280.5 | — | — | ||
| K | 553.7 | 553.6 | 0.1 | delta | |
| F | 536.9 | 536.9 | 0 | Template:Subpage other | |
| max precision | 1 | ||||
| WD | Template:Wikidata Script error: No such module "EditAtWikidata". | Template:Wikidata | |||
| input | C: 280.5, K: white: 553.7, F: 536.9 | ||||
| comment | |||||
| Si ← |
→ S | |
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| Data sets read by {{Infobox element}} | |
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| Name and identifiers | |
| Top image (caption, alt) | |
| Pronunciation | |
| Category (enwiki) | |
| Standard atomic weight | |
| most stable isotope | |
| Natural occurrence | |
| Phase at STP | |
| Oxidation states | |
| Spectral lines image | |
| Electron configuration (cmt, ref) | |
| Term symbol * (cmt, ref) | |
| Wikidata * | |
| * Not used in {{Infobox element}} (2019-02-03) See also {{Infobox element/symbol-to--navbox}} | |
References
- ↑ Meija, Juris; et al. (2016). "Atomic weights of the elements 2013 (IUPAC Technical Report)". Pure and Applied Chemistry. 88 (3): 265–91. doi:10.1515/pac-2015-0305.
- ↑ "Phosphorus: Chemical Element". Encyclopædia Britannica.
- ↑ Wang, Yuzhong; Xie, Yaoming; Wei, Pingrong; King, R. Bruce; Schaefer, Iii; Schleyer, Paul v. R.; Robinson, Gregory H. (2008). "Carbene-Stabilized Diphosphorus". Journal of the American Chemical Society. 130 (45): 14970–1. doi:10.1021/ja807828t. PMID 18937460.
- ↑ Ellis, Bobby D.; MacDonald, Charles L. B. (2006). "Phosphorus(I) Iodide: A Versatile Metathesis Reagent for the Synthesis of Low Oxidation State Phosphorus Compounds". Inorganic Chemistry. 45 (17): 6864–74. doi:10.1021/ic060186o. PMID 16903744.
- ↑ Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
- ↑ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
- ↑ cf. "Memoir on Combustion in General" Mémoires de l'Académie Royale des Sciences 1777, 592–600. from Henry Marshall Leicester and Herbert S. Klickstein, A Source Book in Chemistry 1400–1900 (New York: McGraw Hill, 1952)
One of these is a named reference. It may be cited in the containing article as
- <ref name="CIAAW2013" /> for the source Atomic weights of the elements 2013 (from subtemplates used by {{Infobox element}})
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